Alkynyl gold(I) phosphane complexes: Evaluation of structure–activity-relationships for the phosphane ligands, effects on key signaling proteins and preliminary in-vivo studies with a nanoformulated complex
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چکیده
منابع مشابه
Complexes of germanium(IV) fluoride with phosphane ligands: structural and spectroscopic authentication of germanium(IV) phosphane complexes.
The first phosphane complexes of germanium(iv) fluoride, trans-[GeF(4)(PR(3))(2)] (R = Me or Ph) and cis-[GeF(4)(diphosphane)] (diphosphane = R(2)P(CH(2))(2)PR(2), R = Me, Et, Ph or Cy; o-C(6)H(4)(PR(2))(2), R = Me or Ph) have been prepared from [GeF(4)(MeCN)(2)] and the ligands in dry CH(2)Cl(2) and characterised by microanalysis, IR, Raman, (1)H, (19)F{(1)H} and (31)P{(1)H} NMR spectroscopy. ...
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Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses the application of these catalysts in C-N cross-coupling reactions in the synthesis of heterocycles and pharmaceut...
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A straightforward synthesis of a new hybrid scorpionate ligand [(allyl)2B(CH2PPh2)(Pz)](-) ([A2BPN](-)) is reported. Coordination to rhodium resulted in square-planar complexes [Rh(κ(2)-A2BPN)(L)(L')] [L = L' = (1)/2cod (1,5-cyclooctadiene), CN(t)Bu, CO (6); L = CO, L' = NH3, pyridine, PPh3, PMe3] for which spectroscopic data and the molecular structure of [Rh(κ(2)-A2BPN)(CO)PPh3] (11) indicate...
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Access to catenated and branched polyphosphorus ligands and coordination complexes via a tri(pyrazolyl)phosphane.
We report a convenient and smooth protocol for the high-yielding synthesis of a triphosphane and an iso-tetraphosphane from a readily accessible tri(pyrazolyl)phosphane. The products are obtained from a one-pot reaction at room temperature and form complexes with the Fe(CO)(4)-fragment.
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ژورنال
عنوان ژورنال: Journal of Inorganic Biochemistry
سال: 2016
ISSN: 0162-0134
DOI: 10.1016/j.jinorgbio.2015.12.020